Asymmetric Radical addition of TEMPO to Titanium Enolates
- Degree Grantor:
- University of California, Santa Barbara. Chemistry and Biochemistry
- Degree Supervisor:
- Armen Zakarian
- Place of Publication:
- [Santa Barbara, Calif.]
- Publisher:
- University of California, Santa Barbara
- Creation Date:
- 2014
- Issued Date:
- 2014
- Topics:
- Chemistry, Organic
- Keywords:
- Synthesis,
Oxidations,
Elongates,
Methods,
Stereoselective, and
Free radicals - Genres:
- Online resources and Dissertations, Academic
- Dissertation:
- M.S.--University of California, Santa Barbara, 2014
- Description:
A mild method for α-hydroxylation of N-acyl oxazolidinones by asymmetric radical addition of 2,2,6,6-tetramethylpiperidine N-oxy radical (TEMPO) to titanium enolates was developed. The high diastereoselectivity and broad scope of the reaction show synthetic utility for α-hydroxylation of substrates that are not tolerant to strongly basic conditions.
- Physical Description:
- 1 online resource (118 pages)
- Format:
- Text
- Collection(s):
- UCSB electronic theses and dissertations
- Other Versions:
- http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqm&rft_dat=xri:pqdiss:1584087
- ARK:
- ark:/48907/f3pv6hj8
- ISBN:
- 9781321568172
- Catalog System Number:
- 990045118570203776
- Copyright:
- Phillip Mabe, 2014
- Rights:
In Copyright- Copyright Holder:
- Phillip Mabe
| Access: This item is restricted to on-campus access only. Please check our FAQs or contact UCSB Library staff if you need additional assistance. |